STUDY OF REDUCTION OF TL(I) L-THREONINE COMPLEXES IN AQUEOUS-NONAQUEOUS MEDIA POLAROGRAPHICALLY
Smita Agrawal, Neeru Choudhary and O. D. Gupta*
ABSTRACT
The reduction of Tl(I) L-Threonine complexes has been investigated
electrochemically in aqueous-nonaqueous medium (60% DMF and
60% Ethanol) and the stability constants of complexes have been
evaluated at varying temperatures 308K and 318K. The complexes of
Tl(I) with L-Threonine (1:1 and 1:2) have been reported. Values of
stability constants have been calculated by using DeFord and Hume's
method and the mathematical Mihailov's method has been also applied
for comparison the stability constant values. The changes in
thermodynamic parameters
Keywords: Thallium(I), L-Threonine, stability constant.
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