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Abstract

CONDUTOMETRIC STUDY OF SUBSTITUTED THIOCARBAMIDOPHENOL AT 303. 15K IN ETHANOL WATER MIXTURE.

S.O. Mohod* and D.T. Tayade

ABSTRACT

The subject of this study concern with the complex formation reaction between 2-phenyl thiocarbamidophenol and different transition metal ions at different concentration of solute in ethanol-water mixture at constant temperature by conductometric method. G,k,μ values are determined. The thermodynamic parameters ΔH,ΔG and ΔS for the ion pair formation determine from the value of ion association constant at constant temperature. This measurement revealed that solvent-solvent, solute-solvent and solute-solute interaction and the effects of various substitutents.

Keywords: Substituted thiocarbamidophenols, themodynamic parameters, ion association constant.


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